Five 2,6-Di(pyrazol-1-yl)pyridine-4-carboxylate Esters, and the Spin States of their Iron(II) Complexes
نویسندگان
چکیده
منابع مشابه
Dichlorido(2,6-dipyrazol-1-ylpyridine)zinc(II)
In the title complex, [ZnCl(2)(C(11)H(9)N(5))], the Zn(II) ion assumes a distorted trigonal-bipyramidal ZnN(3)Cl(2) coordination geometry [Zn-N = 2.1397 (16)-2.2117 (17) Å, Zn-Cl = 2.2470 (6) and 2.2564 (6) Å]. The crystal packing exhibits π-π stacking inter-actions between the 2,6-dipyrazol-1-ylpyridine ligands of neighbouring mol-ecules.
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Using one spin-transition to trigger another in solid solutions of two different spin-crossover complexes.
Phase-pure solid solutions of [Co(terpy)(2)][BF(4)](2) and [M(bpp)(2)][BF(4)](2) (M = Fe or Ru, bpp = 2,6-dipyrazol-1-ylpyridine) have been prepared. The spin-state of the [Co(terpy)(2)](2+) dopant is modulated by the spin-state of the [Fe(bpp)(2)](2+) centres in the iron-containing materials.
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ژورنال
عنوان ژورنال: Magnetochemistry
سال: 2019
ISSN: 2312-7481
DOI: 10.3390/magnetochemistry5010009